Ok, I watched the video. It was very clear for the most part (though a little puzzling that he said he wasn't going to use Kirchoff's laws and then proceeded to use Kirchoff's current law to set up his equations! I guess he meant he wasn't going to use both laws together.).
However, if you don't understand how to use matrices, the last part, where he gets the voltages by producing results obtained with a calculator, must seem like black magic! With just two simultaneous equations it's not too difficult to solve the matrix equations by hand (though a little tedious, which is why he just used a calculator). It is worth taking the time to understand enough about matrices so that you don't think it's black magic, even if you do eventually use a calculator or computer software to do the number crunching.
As long as you only deal with two simultaneous equations, it doesn't much matter which approach you take. However, the more simultaneous equations you have to solve, the better it is to adopt a matrix approach (though, inevitably, computer software using advanced numerical solution algorithms are required to do the number crunching for large matrices), so it's worth learning the principles of how to do this with just two.
The following site might help with learning how to solve simultaneous equations using matrices: http://www.mathsisfun.com/algebra/systems-linear-equations-matrices.html