One way to solve this is by substitution:
First, solve the first equation for x by adding y to both sides:
x - y = 2
---> x = y + 2
Then, substitute this expression (y + 2) in for x in the second equation:
4x - 6y = 4
4(y + 2) - 6y = 4
4y + 8 - 6y = 4
-2y + 8 = 4
-2y = -4
y = 2
And if y = 2, x = y + 2 = 2 + 2 = 4 ---> (4, 2)